Search tweets without joined quote with some words


when search tweet without some word, use -word simply source : ( ex some tweets :
1. there is word in this tweet
2. there is noword in this tweet
so we get second tweet.

in my problem, how to find the tweet that no has joined quote with word

   1. there is quote "joined with words
   2. there is no quote in this tweet 

how to doing this?
i have try using - encoding of quote (%22) (so we get second tweets).